3 - What are the main uses of Thiocyanatopropyltriethoxysilane?
3-Mercaptopropyltriethoxysilane has a wide range of uses. In the field of material surface modification, it can be used as a coupling agent. Gain molecules have both ethoxysilane groups that can be affinity with inorganic materials and thiol groups that can react with organic materials. From the perspective of the composite system of inorganic materials and organic materials, the surface of inorganic fillers can be modified after treatment, which is like building a bridge between inorganic materials and organic matrices, strengthening the interfacial bonding force between the two, and improving the comprehensive properties of composites.
In the rubber industry, it also has important functions. Can enhance the interaction between rubber and filler, such as silica filled rubber system, adding this substance can enhance the combination between silica and rubber, improve rubber tensile strength, wear resistance and other physical and mechanical properties, but also reduce the viscosity of the rubber, improve processing performance.
In the field of coatings, it can be used as an adhesion promoter. It forms a chemical bond between the coating and the substrate, enhances the adhesion of the coating to the substrate, makes the coating more stable and durable, and improves the protection and decorative performance of the coating.
In the field of electronic packaging materials, it can optimize material properties. Improve the interface properties between packaging materials and electronic components, enhance moisture and heat resistance and mechanical properties, and ensure the stable operation of electronic components in complex environments.
also has potential applications in the field of biomedical materials. Due to its unique chemical structure, it may be used to modify the surface of biomaterials to regulate the interaction between materials and biomolecules and cells, promote cell adhesion, proliferation, and enhance the biocompatibility of biomaterials.
3 - What are the physical and chemical properties of Thiocyanatopropyltriethoxysilane
3-Mercaptopropyltriethoxysilane has a number of physical and chemical properties. It is a colorless to light yellow transparent liquid with a special odor. The boiling point is quite high, about 217 ° C. Due to the intermolecular force, it boils at a higher temperature. The relative density is nearly 0.985-0.995, which is lighter than water and can float on it when placed in water.
Its solubility is also characteristic, soluble in most organic solvents, such as alcohols, ethers, etc. Due to the molecular structure containing organophilic groups, it is well soluble with organic solvents. However, its solubility in water is limited and only slightly soluble. One end of the Gain molecule is an organic-friendly thiol group and propyl group, and the other end is a hydrolyzable ethoxysilane structure, but the whole is still hydrophobic.
3-mercaptopropyl triethoxysilane has active chemical properties. The ethoxysilane part is easily hydrolyzed in contact with water to generate silanol and release ethanol. The hydrolyzed silanol can be further condensed to form a silicone polymer. This property makes the substance often used as a coupling agent to bridge between inorganic materials and organic materials. The thiol group also has high reactivity and can be added to a variety of compounds containing unsaturated bonds, such as with olefins under the action of initiators, expanding its application in the field of organic synthesis.
3 - What is the synthesis method of Thiocyanatopropyltriethoxysilane
The synthesis of 3-mercaptopropyl triethoxysilane is an important topic in silicone chemistry. The synthesis method often follows the following route.
The starting materials are mostly mercaptopropanol and triethoxysilane. In the reaction system, it is necessary to create a suitable reaction environment with caution. Generally speaking, organic solvents are used as media, such as toluene and xylene, which can disperse the reactants well and promote the smooth progress of the reaction.
During the reaction, acid binding agents such as pyridine and triethylamine are often introduced. The function of acid binding agents is to neutralize the hydrogen chloride generated during the reaction, promote the positive shift of the reaction equilibrium, and improve the yield of the product. Temperature control is also key. Usually in the initial stage of the reaction, it is appropriate to slowly add triethoxysilane to the solution containing mercaptopropanol and acid binding agent at a lower temperature, such as between 0 and 10 ° C. This process requires sufficient stirring to make the reactants contact evenly. After the dropwise addition is completed, the temperature is gradually raised to 30-50 ° C, and the reaction is continued for several times to make the reaction complete.
When the reaction is over, the separation and purification of the product cannot be ignored. The commonly used method is vacuum distillation, which separates the product from the reaction system by the difference in the boiling points of different substances. Compound with a desiccant to remove water to ensure the purity of the product. In this way, high purity 3-mercaptopropyltriethoxysilane can be obtained.
3 - Thiocyanatopropyltriethoxysilane precautions during use
For 3-mercaptopropyltriethoxysilane, there are several ends to pay attention to when using it.
First safety protection. This substance is toxic and irritating to a certain extent, and can be harmful when it touches the skin, eyes, or inhaled or ingested. Therefore, when operating, be sure to wear suitable protective equipment, such as protective gloves, goggles and gas masks, to prevent it from coming into contact with the human body. And the operation should be carried out in a well-ventilated place, so that the volatile gases can be dispersed in time.
Next, pay attention to storage conditions. Store in a cool, dry and well-ventilated place, away from fire and heat sources. Because it is quite sensitive to humidity and easy to hydrolyze and deteriorate when exposed to moisture, it must be sealed and stored to avoid contact with moisture.
Furthermore, during use, it is crucial to accurately control the dosage. According to the specific application and reaction needs, carefully determine the amount of addition. If the dosage is too small, it may be difficult to achieve the desired effect; if the dosage is too large, it may increase the cost and cause other adverse reactions.
In addition, in chemical reactions, the reaction conditions should also be precisely controlled. When this silane participates in the reaction, temperature, pH and other conditions can have a significant impact on the reaction process and product quality. Therefore, the reaction conditions should be finely adjusted according to the reaction characteristics to achieve the best reaction effect.
Repeat, in view of its chemical activity, contact with incompatible substances should be avoided when using. Such as strong oxidants, strong acids, strong bases, etc., contact with them or cause violent reactions, endangering safety. Before use, read the material safety data table carefully to clarify its incompatible substances and prevent problems before they occur.
3 - What is the market price range for Thiocyanatopropyltriethoxysilane?
The market price range of 3-mercaptopropyltriethoxysilane is difficult to determine. The price of this product in the market varies due to various reasons such as quality, origin, and supply and demand.
Looking at the market in the past, those with excellent quality and well-known manufacturers may have high prices. If it is a high-purity grade, it is suitable for high-end fine chemicals and other important places, and the price per kilogram can reach hundreds of yuan.
However, if the quality is ordinary, it is only used for general industrial use, and the origin is sufficient, the price is slightly cheaper. Or it can be obtained for tens of yuan per kilogram.
And changes in market supply and demand also have a great impact on the price. If the demand is strong for a while and the supply is limited, the price will rise; conversely, if the supply exceeds the demand, the price will decline.
For example, in places where chemical raw materials are concentrated, the price is often more affordable due to the convergence of supply, and the competition is quite intense. In remote places, the transportation cost is high, and the price may increase. Therefore, in order to know the exact price, it is necessary to carefully investigate the current market and consult various suppliers to obtain a more accurate number.